Making hemp fabric fire-safe, waterproof, and germ-fighting

Phytic acid-chitosan/silicone polyurethane composite coating: A versatile strategy for flame-retardant, water-repellent, and antibacterial hemp cellulose fabrics.

International journal of biological macromolecules • • Moderately Relevant
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AI Summary

This research focuses on creating advanced coatings for hemp fabric using a combination of phytic acid-modified chitosan and silicone-containing polyurethane. While this paper is primarily a materials science study about textile engineering rather than cannabis pharmacology, it does explore the functional properties of hemp as an agricultural material. The coating technology creates a multilayer structure that dramatically improves the fabric's performance across multiple dimensions: flame retardancy, water resistance, and antibacterial protection. The phytic acid-chitosan component forms a protective barrier that decomposes under heat to create a dense carbon layer, while the silicone component migrates to the surface to provide hydrophobic (water-repelling) properties.

The practical performance improvements are substantial and relevant to industrial applications. The coated hemp fabric achieved a UL-94 V-0 flame rating (the highest fire safety standard) with a limiting oxygen index of 35.1%, while reducing heat release metrics by 65.8% to 80.7% compared to untreated fabric. Simultaneously, the fabric gained excellent water resistance with a contact angle of 133.10° and demonstrated strong antibacterial activity against common pathogens (S. aureus and E. coli). Beyond protective properties, the coating also enhanced mechanical durability, increasing breaking strength by 41.6-40.7% while improving fabric flexibility and softness.

This work demonstrates the potential for hemp as a sustainable textile material when enhanced with functional coatings, opening possibilities for biomedical, home furnishing, and specialized protective textile applications. The durability findings—with 94.2% strength retention after 10 washing cycles—suggest these improvements are practical for real-world use rather than laboratory curiosities.

📄 Original Abstract

In this study, an assembly technique based on phytic acid-modified chitosan (PA-CS) and silicone-containing waterborne polyurethane (SiWPU) was developed to construct of a multifunctional hemp fabric integrating flame retardancy, hydrophobicity, and antibacterial properties. A stable multilayer structure was constructed via hydrogen bonding interactions between the phosphate groups of PA-CS and the urethane groups (-NHCOO-) of SiWPU. Research shows that PA-CS significantly enhances the fabric's thermal stability and decomposes at high temperatures to form a dense carbon layer, raising the limiting oxygen index (LOI) of the hemp fabric to 35.1%, achieving a UL-94 V-0 rating. Compared with the original fabric, the PHRR, HRC, and THR of the PA-CS/SiWPU coated hemp fabric were reduced by 80.7%, 80.7%, and 65.8%, respectively. Simultaneously, the silicon component in SiWPU migrates to the fabric surface, resulting in a water contact angle of 133.10°, demonstrating excellent hydrophobicity and antifouling performance. Furthermore, the coating exhibits remarkable antibacterial activity against S. aureus and E. coli. Following the coating treatment, the breaking strength of the fabric increased by 41.6% (warp) and 40.7% (weft), while the elongation at break improved by 28.6% (warp) and 27.9% (weft). Concurrently, the bending rigidity decreased from 4.93 cN/mm to 3.20 cN/mm, accompanied by a reduction in both static and dynamic friction factors. After 10 washing cycles, the fabric exhibited breaking strength retention rates of 94.2% (warp) and 89.1% (weft). This study opens a new avenue for the high-value-added and multifunctional utilization of hemp fabrics, demonstrating great application potential in fields including home, biomedical, and smart textiles.

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